(E)-1-{4-[Bis(4-bromophenyl)methyl]piperazin-1-yl}-3-(4-ethoxy-3-methoxyphenyl)prop-2-en-1-one

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(E)-3-(4-Meth­oxy­phen­yl)-1-[4-(piperidin-1-yl)phen­yl]prop-2-en-1-one

The piperidine ring in the title compound, C(21)H(23)NO(2), is in a slightly distorted chair conformation. The dihedral angle between the two benzene rings is 5.6 (4)°. The dihedral angles between the propenone unit and the benzene and meth-oxy-substituted benzene rings are 5.6 (7) and 10.7 (8)°, respectively. Weak inter-molecular C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions contribute to ...

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(S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one

The title compound, C(15)H(16)ClNO(3)S, was obtained by the organocatalytic asymmetric Michael addition of thian-4-one to 1-chloro-4-[(1E,3E)-4-nitro-buta-1,3-dien-yl]benzene. The double bond has an E configuration and the thian-4-one six-membered ring adopts a chair conformation. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.

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(E)-1-(2-Methyl-4-phenyl­quinolin-3-yl)-3-phenyl­prop-2-en-1-one

In the title compound, C(25)H(19)NO, the quinoline ring system is approximately planar, with a maximum deviation of 0.32 (1) Å, and forms dihedral angles of 80.74 (3) and 81.71 (4)° with the two phenyl rings. In the crystal. mol-ecules are stacked along the b axis by way of a C-H⋯π inter-action and a weak π-π inter-action between the pyridine and phenyl rings with a centroid-centroid distance o...

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(E)-1-{4-[Bis(4-bromo­phen­yl)meth­yl]piperazin-1-yl}-3-(4-eth­oxy-3-meth­oxy­phen­yl)prop-2-en-1-one

In the title mol-ecule, C(29)H(30)Br(2)N(2)O(3), the piperazine ring has a chair conformation and the C=C double bond has an E conformation. The dihedral angle between the bromo-benzene rings is 79.1 (3)°. In the crystal, mol-ecules are linked through C-H⋯O and C-H⋯Br hydrogen bonds.

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(E)-1-{4-[Bis(4-meth­oxy­phen­yl)meth­yl]piperazin-1-yl}-3-(4-eth­oxy-3-meth­oxy­phen­yl)prop-2-en-1-one

In the mol-ecule of the title compound, C(31)H(36)N(2)O(5), the piperazine ring displays a chair conformation. The dihedral angle between the benzene rings of the bis-(4-meth-oxy-phen-yl)methyl group is 83.42 (15)°. In the crystal, centrosymmetric-ally related mol-ecules are linked through pairs of C-H⋯O hydrogen bonds into dimers, generating an R(2) (2)(10) ring motif. The dimers are further c...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811052123